Battery Life Time Management

ABSTRACT

A method for managing the lifetime of a battery is disclosed herein. An ambient temperature is measured near a battery. A discharge of the battery is triggered when the ambient temperature exceeds a first temperature threshold. The battery can then be charged when the ambient temperature decreases below a second temperature threshold.

This application claims the priority benefit of French patentapplication Ser. No. 13/55209, filed on Jun. 6, 2013, and French patentapplication Ser. No. 13/55211, filed on Jun. 6, 2013, the contents ofwhich is hereby incorporated by reference in its entirety to the maximumextent allowable by law.

TECHNICAL FIELD

The present invention relates generally to electronic systems andmethods, and, in particular embodiments, to battery life timemanagement.

BACKGROUND

Documents U.S. Pat. No. 5,705,293, U.S. Publication No. 2007/0184345,and European Application No. EP2310502 describe examples ofmicrobatteries.

Many types of microbatteries, used in self-contained fashion (forexample, in the form of button cells) or directly implanted on printedcircuits, are known. Certain microbatteries are rechargeable.

Documents U.S. Pat. No. 6,027,076 and U.S. Pat. No. 8,047,316 describemethods and systems for managing Li-Ion batteries to increase theirlifetime.

SUMMARY OF THE INVENTION

Embodiments of the present invention relate to a method and a device forregenerating the charge capacity of a battery. Embodiments also relateto a so-called solid-state battery.

An embodiment provides a method for regenerating the charge capacity ofa microbattery which overcomes all or part of the disadvantages of priorart.

Another embodiment, according to a first aspect, regenerates the chargecapacity of a microbattery.

Another embodiment, according to a second aspect, improves the lifetimeof a microbattery.

A method for managing the lifetime of a battery is provided, wherein adischarge of the battery is triggered when the ambient temperatureexceeds a first threshold.

The foregoing and other features and advantages will be discussed indetail in the following non-limiting description of specific embodimentsin connection with the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 very schematically shows an example of usual microbattery, ofso-called all-solid-state thin-film lithium type;

FIGS. 2 and 3 are curves illustrating an example of aging of storedmicrobatteries, according to the ambient temperature and to the initialcharge conditions;

FIG. 4 very schematically shows an embodiment of a method forregenerating the charge capacity of a microbattery according to a firstaspect;

FIG. 5 illustrates, in the form of timing diagrams, the operation of themethod of FIG. 4;

FIG. 6 very schematically shows an embodiment of a method forcontrolling the charge capacity of a microbattery according to the firstaspect;

FIG. 7 shows an embodiment of an electronic system for controlling amicrobattery;

FIG. 8 shows an embodiment of a device with a main and a secondarymicrobattery;

FIG. 9 is a variation of FIG. 7, capable of using the system of twomicrobatteries shown in FIG. 8;

FIG. 10 very schematically shows an embodiment of a method for managingthe lifetime of a microbattery according to a second aspect; and

FIG. 11 illustrates, in the form of timing diagrams, the operation ofthe method of FIG. 10.

DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS

The same elements have been designated with the same reference numeralsin the different drawings, which have been drawn out of scale. Forclarity, only those steps and elements which are useful to theunderstanding of the described embodiments have been detailed. Inparticular, the specific structure of a circuit for controlling thecharge or discharge of a battery and of its secondary data storagecircuits has not been detailed, the described embodiments beingcompatible with the use of current electronic systems, for example,based on a microcontroller.

A method for managing the lifetime of a battery is disclosed herein. Forexample, a discharge of the battery is triggered when the ambienttemperature exceeds a first threshold.

According to an embodiment, a step of charge of the battery is carriedout when the ambient temperature decreases below a second threshold.

According to an embodiment, the discharge of the battery is performeduntil a third threshold is reached.

According to an embodiment, the third threshold corresponds to less than20%, preferably on the order of 5%, of the nominal charge of the batterywhen new.

According to an embodiment, the discharge step is followed by a batterystep of biasing of the battery by applying there across a bias voltagelower than the minimum threshold voltage necessary to charge thebattery.

According to an embodiment, the voltage is selected to correspond tofrom 30% to 50% of the voltage necessary to charge the battery.

According to an embodiment, the battery is of all-solid-state thin-filmlithium type.

According to an embodiment, the first threshold is approximately 47° C.

According to an embodiment, the second threshold is approximately 65° C.

According to an embodiment, a device of the type converting power bythermoelectric effect replaces the battery during at least part of thedischarge step.

According to an embodiment, the power converter is a Seebeck-effectpower converter.

According to an embodiment, at least one threshold and/or the biasvoltage is programmable.

According to an embodiment, a device for managing the lifetime of abattery in operation in a system is provided.

The above-described embodiments refer to the case of microbatteriesformed in a thin film based on materials comprising lithium. Theyhowever apply to any type of batteries having an aging process followinga similar pattern. In the present disclosure, terms microbattery andbattery are equivalently used.

The ambient temperature, the charge and discharge state significantlyinfluence the variation of the battery charge capacity. Further, thecharge capacity performances of microbatteries depend on theenvironmental conditions, on the storage conditions, and on theoperating conditions.

It would be desirable to lengthen the lifetime of a microbattery byplacing it in optimal conditions of use, enabling to maintain asignificant charge capacity all along the battery service life andlifetime.

It would also be desirable to be able to predict the aging of amicrobattery according to its utilization mode and to be able to detectand to report the fact that its charge capacity becomes insufficient.

An embodiment of the present disclosure provides a discharge of thebattery according to certain conditions of use or of storage and/oraccording to parameters such as temperature.

FIG. 1 is a simplified cross-section view of a usual microbattery 1 ofso-called all-solid-state thin-film lithium type. The battery is formedon a substrate 10, in certain cases covered with an insulating layer 11,for example, made of silicon oxide. A cathode current collector layer12, for example, made of platinum, is deposited on insulating layer 11.Above cathode current collector 12 is arranged a positive electrodelayer 13 (CATHODE FILM), for example, made of lithiated cobalt oxide. Anelectrolyte 14 (ELECTROLYTE FILM) is deposited on layer 13. It may forexample be formed of a compound of lithium and phosphorus oxynitride(LiPON).

Above electrolyte 14 extends a negative electrode layer 15 (ANODE FILM),which may be formed, for example, of metal lithium, of silicon, or ofgermanium. Layer 15 is topped with an anode current collector layer 16,for example, made of copper. In certain cases, for example, so-calledhigh-temperature batteries, cathode and anode current collector layers12 and 16 are locally topped, respectively, with a cathode contact pad17 and with an anode contact pad 18. In the example of FIG. 1, layer 16extends on one side of the structure to reach layer 11 and extendthereon. The structure thus formed is covered with a passivation layer,not shown. Typically, such a battery has a thickness of a few microns ortens of microns and a surface area on the order of one cm2.

European patent Application No. EP2301502 describes an example ofbattery of lithium-ion type as well as its manufacturing principle.

During the charge of this type of battery, lithium ions displace fromthe positive electrode to negative electrode 15, while during thedischarge, lithium ions displace in the reverse direction.

The materials of the positive, electrolyte, and negative electrodelayers are selected according to the voltage which is desired to beobtained across the battery and according to the desired applicationthereof. For example, certain batteries comprise a positive electrodemade of lithium cobalt (LiCoO₂), other comprise a positive electrodebased on titanium oxysulfide (TiOS), etc. Still as an example, thenegative electrode may be made of lithium and the electrolyte may be ofLiPON (lithium phosphorus oxynitride) type. As a variation, the negativeelectrode is formed by means of amorphous compounds and of lithium, forexample, silicon or germanium and lithium, the amorphous material thenbecoming conductive under the influence of lithium during the batteryoperation.

As a specific example of embodiment, a LiPON battery with a positiveLiCoO₂ electrode has a nominal 4.2-volt voltage and an operating rangelocated between a few degrees and approximately 100° C.

Microbatteries are advantageously used due to their high miniaturizationand to their high charge capacity relative to the occupied volume. Whenthese microbatteries are rechargeable, their lifetime becomes muchgreater than that of their non-rechargeable equivalents, since hundredsor thousands or charge-recharge cycles can then be performed.

However, a progressive aging of these batteries can be observed, whichtranslates as a progressive decrease in the charge capacity. Even in thecase where a charged cattery is not used, that is, in the case ofabsence, there across, of a load into which it can supply current, aprogressive discharge occurs, forcing to carry out a charge operationbefore use.

The inventors have observed that the aging phenomenon is all the fasteras the ambient temperature to which the microbattery is submitted ishigh, be it in storage mode or in operation.

FIG. 2 shows typical aging curves of a lithium microbattery according totemperature, in storage mode, the microbattery being initially chargedat 100% of its capacity. Time t in hours appears in abscissa accordingto a logarithmic scale, over a time period of approximately 10 years.The scale of ordinates shows the charge capacity loss percentage CCL ofthe battery as compared with a new state where the battery is assumed tohave a 100% charge capacity.

The three curves of FIG. 2 respectively correspond to ambienttemperatures of 80° C. (curve 22), of 60° C. (curve 24), and of 30° C.(curve 26). The variation of the charge capacity loss is of exponentialtype. For example, the curve at 60° C. shows a 30% charge capacity lossafter 2,000 hours and a 70% loss after 20,000 hours.

FIG. 3 shows typical curves of aging in storage of an initially chargedlithium microbattery according to its storage time, for a 60° C. ambienttemperature. As in FIG. 2, time t in hours appears in abscissa accordingto a logarithmic scale, over a time period of approximately 10 years,and the scale of ordinates shows charge capacity loss percentage CCL.

FIG. 3 illustrates six examples (six curves) 31 to 36, eachcorresponding to a different initial charge level, respectively 100%(curve 31), 90% (curve 32), 80% (curve 33), 72% (curve 34), 66% (curve35), and 33% (curve 36). Here again, the variation of the chargecapacity loss is of exponential type. For example, curve 34 for aninitial 72% charge shows a charge capacity loss of approximately 10%after 1,500 hours of storage, of approximately 30% after 10,000 hours,and of approximately 60% after 50,000 hours. The lower the initialcharge level, the lower the charge capacity loss. For example, thecharge capacity loss after approximately 10,000 hours of storage is 10%for an initial charge of 33% of the full charge capacity, of 25% for aninitial 66% charge, and of close to 60% for an initial 100% charge.

These observations show that the aging of this type of microbattery isall the faster as the temperature to which the microbattery is submittedis high.

They also illustrate the problem of the possible aging of microbatteriesin storage. A battery, even new, may have a short lifetime if it hasbeen stored charged for a long time.

The inventors have observed that the charge capacity of this type ofmicrobattery may be partially preserved after a microbattery dischargeoperation, and this more or less rapidly and more or less efficientlyaccording to the discharge conditions (current-vs.-voltage curve imposedby the discharge means) and to the environmental conditions (ambienttemperature).

According to a first aspect, the inventors have also observed that apartial regeneration of the structure of the negativeelectrode-electrolyte-positive electrode layers of this type ofmicrobattery is made possible by applying thereto a low forward biasvoltage for a relatively long time, for example, from a few hours to afew tens of hours, while the battery is discharged. This method enablesto recover a significant charge capacity, on the order of 50% of thecharge capacity lost between the time when the battery was completelycharged and the time when it has discharged.

Complex electrochemical phenomena are involved. The inventors assumethat this method enables to act on the crystal structure of the positiveelectrode.

FIG. 4 very schematically shows, in the form of blocks, an embodiment ofa method for regenerating the charge capacity of a microbattery. A firststep 41 (DISCHARGE) is a battery discharge operation. During thisdischarge operation, the battery charge level is periodically measuredand compared (block 43, CHARGE=LTH?) with a minimum charge thresholdLTH. As long as this threshold has not been reached (output N of block43), the discharge operation is continued. As soon as threshold LTH isreached (output Y of block 43), a step 45 (POLAR VPOL) of forwardbiasing of the battery under a low voltage VPOL is carried out.

The actual discharge operation is performed by any appropriatemechanism. For example, the discharge current is controlled for a firstportion of the step, after which the discharge voltage is controlled forthe rest of the step. Such a discharge operation is performed until thebattery has a residual charge level LTH lower than 20%, preferably lowerthan 10%, or even than 5%, of the nominal charge level, measured whenthe battery is new. “Nominal charge” means the maximum charge of thebattery, in environmental conditions corresponding to the operationconditions of use specified for the battery.

The threshold (LTH) is for example experimentally determined accordingto the charge capacity which is desired to be recovered and to thedurations of discharge step 41 and of biasing step 45, selectedaccording to the system powered by the battery. Many solutions fortesting the residual charge level of a battery during the discharge stepare known. For example, the battery is made to supply current to acalibrated load and the charge current and voltage parameters aremeasured.

Battery biasing step 45 comprises imposing across the battery a forwardvoltage VPOL, which is low as compared with its nominal operatingvoltage. For example, in the case of an all-solid-state thin-filmlithium battery having a 4.2-volt nominal voltage, voltage VPOL isselected to be between 2 and 3.6 volts. More generally, voltage VPOLcorresponds to less than 85%, preferably less than 50% of the nominalvoltage. To avoid damaging the battery, this voltage however preferablyremains greater than 45% of the nominal voltage.

The duration of the biasing step depends on the characteristics of thebattery and on the ambient temperature conditions. This duration is forexample a few tens of hours. In practice, this duration is adapted tothe time necessary for the regeneration and is typically determinedexperimentally.

A quantity on the order of 50% of the charge capacity lost during theregeneration operation, in the case where the battery was fully chargedat the beginning of this operating period and discharged at the end ofthis same period, can thus be recovered.

FIG. 5 shows timing diagrams illustrating the regeneration method andits microbattery charge-discharge-biasing cycles. A first timing diagram52 shows the times at which the discharge is triggered, in the form ofstart pulses 521. A second timing diagram 54 shows the course of themicrobattery charge. A third timing diagram 56 shows the course ofvoltage VBAT across the battery.

Four cycles are shown in FIG. 5, where it should be noted that thebattery capacity at full charge 531 decreases along time, this being dueto the fact that the regeneration is not complete. Each cycle iscomprised of the three following steps: operating step W capable ofcontaining an initial charge operation, forced discharge step 41 down tolevel LTH, and step 45 of biasing under low voltage VPOL for which thecharge level remains substantially steady. Voltage VBAT is nominal(value VNOM) during operating step W, progressively decreases duringdischarge step 41, and corresponds to imposed value VPOL during thebiasing step. The course of the voltage during discharge step 41 mayvary according to the discharge process used.

Start pulses 521 may be conditioned by different types of events, and bythe operational conditions of the system powered by the battery. Forexample, the exceeding of an ambient temperature threshold triggers thedischarge operation. According to another example, the discharge processis triggered after a determined operating time. It is also possible toperiodically test the charge level during the battery operation and totrigger the discharge operation when the charge level decreases below athreshold. Other triggering conditions or even a combination ofdifferent conditions may also be envisaged.

According to the characteristics of the battery, and to the desiredoperating mode, especially to take into account the requirements of thesystem powered by the battery in terms of availability thereof, biasvoltage VPOL may be settable.

In many cases, systems using microbatteries are monitoring or controlsystems which need to have an availability and reliability guaranteedfor a long period. Since the microbattery regeneration process is notcomplete, the battery aging is strongly decreased, but not totallysuppressed.

It would be desirable to detect the battery aging level to be able tointervene on the system using it, or to determine whether a storedbattery is capable of being inserted into a system or, for example, toreplace the battery when its charge capacity decreases below a giventhreshold.

FIG. 6 very schematically shows, in the form of blocks, an embodiment ofa method for controlling the charge capacity of a microbattery. A firststep 61 (CC MEAS) comprises measuring the battery charge capacity. Then(test 63, CC<CTH?) charge capacity CC is compared with a threshold CTH.As long as the charge capacity remains greater than this threshold(output N of block 63), the aging is considered not to be critical(block 65, BAT OK). As soon as threshold CTH is reached (output Y ofblock 63), a signal corresponding to the detection of a low chargecapacity is generated (block 67, LOW CAP). This signal may be used indifferent ways, for example, to report the need to replace the battery.

Measurement step 61 for example comprises measuring the time necessaryfor a discharge into a calibrated load from a known initial chargestate. Threshold CTH is set, for example, to 10% of the initial chargecapacity of the battery when new, preferably to 5%. Other thresholds maybe selected according to the accuracy of the measurement, to thecriticality of the availability of the system using the battery, or onother criteria associated with the application, such as the delaynecessary to replace the battery.

According to an embodiment, the method of FIG. 6 is implementedperiodically. The periodicity may for example be of one measurementafter each operation of discharge and biasing of the method of FIG. 4.As a variation, the measurement of the charge capacity may be measuredcyclically, for example, every 100 hours. According to anothervariation, the measurement is performed during periods when the batteryis not necessary for the system operation (case, for example, of asystem having a back-up battery or another power supply means).

The above-described embodiments can be implemented when the battery isin place in an electronic system that is it likely to power.

As a variation, such solutions may be applied to a battery in storage,in the form of periodic maintenance operations. For example, anelectronic control device may be provided in the form of a test packageof battery charger type.

FIG. 7 very schematically shows, in the form of functional blocks, anexample of an electronic system 7 for controlling a microbattery. Manyvariations of such a system can exist. Only those elements which aremost representative of a control device especially allowing steps ofdischarge and biasing of a microbattery have been illustrated.

Microbattery 1 (BAT) is connected to a load 2 (LOAD) that it powers.Control system 7 is driven by a microcontroller 71 (μC) having resourcesusual for this type of device added thereto, for example, a programmemory 712 (PROG MEM) and a parameter memory 714 (PARAM MEM), and aclock mechanism 716 (TIMER). A unit 718 (DISPLAY) indicative of thebattery state may be added thereto. Parameter memory 714 especiallyenables to store the parameters used in the implementation of methodsfor regenerating the battery charge capacity. In particular, accordingto an embodiment, the different thresholds and threshold levels areprogrammable. Different units of sensor or actuator type enable toperform the operation (block 72, DISCHARGE) of discharge of battery 1,to measure (unit 73, VOLTAGE MEASURE) the voltage there across, to forcea bias voltage (unit 74, POLAR) there across, or also to measure theambient temperature (unit 75, TEMP SENSOR). The different unitscommunicate and are connected to one or several control and dataexchange buses 76.

For its operation, control device 7 itself requires being powered by apower source. For example, device 7 is connected to a main electricpower source such as the mains and microbattery 1 ensures secondaryfunctions. According to another example, the system is capable,according to its environmental conditions, of sampling all or part ofits operating power from its environment by conversion of thermal,mechanical, electromagnetic power, etc.

Device 7 may be a sub-system implanted within an electronic unit poweredby battery 1, or may be a self-contained device used to test and toregenerate batteries encapsulated in a package, for example, in the formof button cells.

According to an alternative embodiment, an auxiliary power supply device79 (AUX POWER SUP) comprising an auxiliary battery coupled (connection791 in dotted lines) to battery 1 is used. The auxiliary battery chargeoperation is performed by battery 1 when operating.

FIG. 8 is a top view of an example of device 8 formed of a mainmicrobattery 81 (MAIN BAT) and of a secondary microbattery 83 (SEC BAT)placed on the main battery. Batteries 81 and 83 are preferably formed ona common substrate. FIG. 8 shows positive electrodes 812 of the mainbattery and 832 of the secondary battery, as well as negative electrode814 common to the two batteries.

Battery 83 may be substituted to battery 81 when the latter undergoes adischarge and biasing operation according to one of thepreviously-described methods. Battery 83 can thus temporarily power asystem using battery 81 and thus avoid any operating loss. Such acombination has many advantages, especially in terms of bulk, ofmanufacturing cost, of simplification of the control electronics.

Preferably, secondary battery 83 is itself submitted to a discharge andbiasing process, or even to a process of measurement of the chargecapacity, such as described hereabove.

FIG. 9 very schematically shows in the form of functional blocks anexample of electronic device 9 using a main microbattery 81 and asecondary microbattery 83, for example, of the type illustrated in FIG.8. As a variation, the microbatteries are separated.

Device 9 shows the elements of the system of FIG. 7. For example,batteries 81 and 83 are connected via a relay 91 (RELAY) or the like toload 2, so that a single one of the two batteries is connected thereto(connection 92) at a given time to power the load, the othermicrobattery being then connected (connection 93) to control device 9.Device 9 has a unit 94 (SELECT) connected (connection 95) to the coil ofrelay 91 that it controls under control of microcontroller 71.

In this example, control device 9 is itself powered by that of the twobatteries which powers load 2, which avoids providing an auxiliarybattery.

As for the embodiment of FIG. 7, system 9 may further be connected to amain electric power source such as the mains, it may be capable,according to the environmental conditions, to sample or part of itsoperating power from its environment, by conversion of thermal,mechanical, electromagnetic power, etc.

According to a second aspect, the aging being faster in operating mode(battery supplying a load) and at higher temperature, it may beappropriate to monitor the ambient temperature and to cause a dischargewhen the temperature exceeds a threshold. As a specific example, thisthreshold is approximately 60° C. in the case of a LiPON electrolytemicro-battery.

FIG. 10 shows, in the form of blocks, an embodiment of a regenerationmethod taking into account this second aspect, that is, a cyclic methodof the type charging-discharging a microbattery according to the ambienttemperature.

FIG. 11 illustrates, in timing diagrams, an example of implementation ofthis embodiment. A first timing diagram 112 shows the variations oftemperature T. A second timing diagram 114 shows the variation of thebattery charge.

According to this embodiment, it is provided to monitor the ambienttemperature with respect to two thresholds, respectively high, HT, andlow, LT. For example, the temperature is compared with the low threshold(block 102, T>LT?). When the temperature increases and reaches (output Yof block 102; time t1, FIG. 11) threshold LT, discharge 41 of thebattery is triggered. For example, the discharge carries on until aminimum threshold is reached (output Y of block 43), for example,threshold LTH described in relation with FIG. 5. Preferably, thedischarge operation is followed by a biasing operation such as describedin relation with FIG. 5 (block 45 in dotted lines in FIG. 10).

The temperature decrease is then monitored by comparing it with the highthreshold (block 104, T<HT?). When the temperature falls back belowthreshold HT (output Y of block 104; time t2, FIG. 11), the battery isthen set back to the charge mode (block 106) until it reaches itsmaximum charge capacity.

Although this has not been shown in FIG. 10, if the temperature remainsbetween the two thresholds for a given time period, a new discharge istriggered. The time period is for example set between a few hours and20-30 hours, for example, on the order of 12 hours. Further, if during atemperature decrease, the temperature does not decrease back belowthreshold LT, and increases beyond threshold HT, a discharge step isalso triggered.

While the battery is being discharged, it has to be replaced withanother power source to power the system (load 2) to which it isconnected and that it is supposed to power. This power supply means forexample is a system for converting thermal power into electric power, ofSeebeck converter type. Such an embodiment takes advantage of the factthat the battery discharge is triggered when the ambient temperature ishigh, and thus when the Seebeck converter can operate. Any otherreplacement power supply mode may also be envisaged depending on thecharacteristics of the system using the battery.

Threshold HT for starting the charge is preferably selected to begreater than threshold LT for starting a discharge, in order to takeinto account thermal inertia phenomena and to leave time for the batteryto recharge before it becomes necessary for the system power supply(case of a replacement source of Seebeck converter type, for example).As a specific embodiment, thresholds LT and HT are respectivelyapproximately 47° C. and 61° C.

The above operation is repeated along the battery lifetime.

Different embodiments with different variations have been describedhereabove. It should be noted that those skilled in the art may combinevarious elements of these various embodiments and variations withoutshowing any inventive step. Further, the practical implementation of thedescribed embodiments is within the abilities of those skilled in theart based on the functional indications given hereabove and by usingtools usual per se.

Such alterations, modifications, and improvements are intended to bepart of this disclosure, and are intended to be within the spirit andthe scope of the present invention. Accordingly, the foregoingdescription is by way of example only and is not intended to belimiting. The present invention is limited only as defined in thefollowing claims and the equivalents thereto.

1-25. (canceled)
 26. A method for regenerating charge capacity of abattery, the method comprising: causing the battery to discharge; andafter causing the battery to discharge, applying a bias voltage acrossthe battery, the bias voltage being smaller than a minimum voltagenecessary to charge the battery.
 27. The method of claim 26, wherein thebias voltage has a value that is 30% to 50% of the minimum voltagenecessary to charge the battery.
 28. The method of claim 26, whereincausing the battery to discharge comprises causing the battery todischarge to a first threshold.
 29. The method of claim 28, wherein thefirst threshold corresponds to less than 20% of a nominal charge of thebattery when new.
 30. The method of claim 29, wherein the firstthreshold corresponds about 5% of the nominal charge of the battery whennew.
 31. The method of claim 28, wherein the first threshold isprogrammable.
 32. The method of claim 26, further comprising: measuringa charge capacity of the battery; and comparing the measured chargecapacity to a second threshold.
 33. The method of claim 32, wherein thesecond threshold corresponds to less than 10% of a nominal charge of thebattery when new.
 34. The method of claim 33, wherein the secondthreshold corresponds about 5% of the nominal charge of the battery whennew.
 35. The method of claim 32, wherein the second threshold isprogrammable.
 36. The method of claim 26, wherein causing the battery todischarge comprises causing the battery to discharge when an ambienttemperature exceeds a third threshold.
 37. The method of claim 36,wherein the third threshold is programmable.
 38. The method of claim 26,wherein the battery comprises an all-solid-state thin-film lithium typebattery.
 39. The method of claim 26, wherein the steps of causing thebattery to discharge and applying the bias voltage across the batteryare implemented during operation of the battery.
 40. The method of claim26, wherein the steps of causing the battery to discharge and applyingthe bias voltage across the battery are implemented during storage ofthe battery.
 41. The method of claim 26, wherein the bias voltage isprogrammable.
 42. A method comprising: using a primary battery toprovide power to a load; regenerating a charge capacity the primarybattery by causing the battery to discharge and, after causing thebattery to discharge, applying a bias voltage across the battery, thebias voltage being smaller than a minimum voltage necessary to chargethe battery; and using a secondary battery to provide power to the loadwhile regenerating the charge capacity of the primary battery.
 43. Themethod of claim 42, wherein the primary battery and the secondarybattery are disposed on a common substrate.
 44. The method of claim 42,further comprising: causing the second battery to discharge; and aftercausing the second battery to discharge, applying a second bias voltageacross the second battery, the second bias voltage being smaller than aminimum voltage necessary to charge the second battery.
 45. A deviceoperable with a battery, the device comprising: a discharge circuitconfigured to cause the battery to discharge; and a bias circuitconfigured to apply a bias voltage across the battery, the bias voltagebeing smaller than a minimum voltage necessary to charge the battery.46. The device of claim 45, further comprising: a microcontrollerconfigured to control the discharge circuit and the bias circuit;program memory coupled to the microcontroller; parameter memory coupledto the microcontroller; and a clock mechanism coupled to themicrocontroller.
 47. The device of claim 46, further comprising a sensoror measurement unit coupled to the microcontroller.
 48. The device ofclaim 47, wherein the sensor or measurement unit comprises a temperatureunit.
 49. The device of claim 47, wherein the sensor or measurement unitcomprises a voltage unit.
 50. The device of claim 47, wherein themicrocontroller configured to control the discharge circuit and the biascircuit based on physical information received from the sensor ormeasurement unit and threshold information stored in the parametermemory.